論文発表

グループ共同
    2021年
  1. Synthesis, Characterization, and Formation of Self-Assembled Monolayers of a Phosphonic Acid Bearing a Vinylene-Bridged Fluoroalkyl Chain
    Shirai, T.; Yamauchi, S.; Kikuchi, H.; Fukumoto, H.; Tsukada, H.; Agou, T. Appl. Suf. Sci.DOI: 10.1016/j.apsusc.2021.151959.
  2. Synthesis and photoluminescence properties of fluorine-containing poly(phenylene vinylene) bearing hexaflurocyclopentene-fused phenanthrene unit
    Fukumoto, H.; Shiitsuka, K.; Yamada, K.; Yamada, S.; Konno, T.; Kubota, T.; Agou, T. Polym. Int. DOI: 10.1002/pi.6291.
  3. Fused-Nonacyclic Multi-Resonance Delayed Fluorescence Emitter Based on Ladder-Thiaborin Exhibiting Narrowband Sky-Blue Emission with Accelerated Reverse Intersystem Crossing
    Nagata, M.; Min, H.; Watanabe, E.; Fukumoto, H.; Mizuhata, Y.; Tokitoh, N.; Agou, T.; Yasuda, T. Angew. Chem. Int. Ed. 2021, 60, 20280-20285. DOI: 10.1002/anie.202108283. Selected as a "HOT PAPER"!
  4. Synthesis, Structure, and Surface Properties of Polyacrylates Poly(meth)acrylates Bearing a Vinylene-Bridged Fluoroalkyl Side Chain
    Shirai, T.; Fukumoto, H.; Kanno, Y.; Kubota, T.; Agou, T. Polymer 2021, 217, 123478. DOI:10.1016/j.polymer.2021.123478.
  5. 2020年
  6. Synthesis of Carbazole-Fused Azaborines via a Pd-Catalyzed C-H Activation-Cyclization Reaction
    Nagata, M.; Oshiro, T.; Mizuhata, Y.; Tokitoh, N.; Hosoya, T.; Yamada, S.; Konno, T.; Fukumoto, H.; Kubota, T.; Agou, T. Bull. Chem. Soc. J. 2020, 94, 21-23. DOI: 10.1246/bcsj.20200129.
  7. Visible-Transparent Aromatic Polymers Obtained by the Polycondensation of a Bis(trifluorovinyl)benzene with Bisphenols
    Agou, T.; Yoshinari, K.; Shirai, T.; Yamada, S.; Konno, T.; Mizuhata, Y.; Tokitoh, N.; Yasuda, S.; Yamazaki, T.; Fukumoto, H.; Kubota, T. Macromolecules 2020, 53, 2942-2949. DOI: 10.1021/acs.macromol.0c00157.
  8. Facile preparation of α,ω-diynes bearing a perfluoroalkylene linker -(CF2)n- (n=4,6) and their application for Co- or Rh-catalyzed [2+2+2]cycloaddition reactions affording aromatic compounds with perfluoroalkylene units
    Agou, T.; Saruwatari, S.; Shirai, T.; Kumon, T.; Yamada, S.; Konno, T.; Mizuhata, Y.; Tokitoh, N.; Sei, Y.; Fukumoto, H.; Kubota, T. J. Fluorine Chem. 2020, 234, 109512. DOI: 10.1016/j.jfluchem.2020.109512.
  9. Helicenes Fused with Hexafluorocyclopentene (HFCP): Synthesis, Structure, and Properties
    Agou, T.; Kohara, M.; Tamura, Y.; Yamada, K.; Shiitsuka, K.; Hosoya, T.; Mizuhata, Y.; Tokitoh, N.; Hayashi, Y.; Moronuki, Y.; Ishii, A.; Tanaka, Y.; Muranaka, A.; Uchiyama, M.; Yamada, S.; Konno, T.; Fukumoto, H.; Kubota, T. Eur. J. Org. Chem. 2020, 1871-1880. DOI: 0.1002/ejoc.202000152.
  10. Pentacyclic Ladder-Heteraborin Emitters Exhibiting High-Efficiency Blue Thermally Activated Delayed Fluorescence with an Ultrashort Emission Lifetime
    Agou, T.; Matsuo, K.; Kawano, R.; Park, I. S.; Hosoya, T.; Fukumoto, H.; Kubota, T.; Mizuhata, Y.; Tokitoh, N.; Yasuda, T. ACS Mater. Lett. 2020, 2, 28-34. DOI: 10.1021/acsmaterialslett.9b00433.
  11. 2019年
  12. Phosphines featuring a hexafluorocyclopentene skeleton: Synthesis, coordination properties, and applications for Lewis-acidic transtion-metal catalysts
    Agou, T.; Wada, N.; Komatsu, M.; Nohara, M.; Mizuhata, Y.; Tokitoh, N.; Hosoya, T.; Fukumoto, H.; Kubota, T. Results in Chemistry 2019, 1, 100008. DOI: 10.1016/j.rechem.2019.100008.
  13. Synthesis and properteis of perfluoroalkylated TIPS-pentacenes
    Agou, T.; Suzuki, S.; Kanno, Y.; Hosoya, T.; Fukumoro, H.; Mizuhata, Y.; Tokitoh, N.; Suda, Y.; Furukawa, S.; Saito, M.; Kubota, T. Tetrahedron 2019, 75, 130678. DOI: 10.1016/j.tet.2019.130678.
  14. 2018年
  15. Fluorine-Containing Dibenzoanthracene and Benzoperylene-Type Aromatic HydroCarbons: Synthesis, Structure, and Basic Chemical Properties
    Gotsu, O.; Shiota, T.; Fukumoto, H.; Kawasaki-Takasuka, T.; Yamazaki, T.; Yajima, T.; Agou, T.; Kubota, T. Molecules 2018, 23, 3337. DOI: 10.3390/molecules23123337.
  16. Effective synthesis of fluorine-containing phenanthrene bearing hydroxyl group using Mallory reaction and its application for fluorinated polymers
    Kataoka, S.; Fukumoto, H.; Kawasaki-Takasuka, T.; Yamazaki, T.; Nishimura, K.; Agou, T.; Kubota, T. J. Fluorine Chem. 2018, 218, 84-89. DOI: 10.1016/j.jfluchem.2018.11.017.
  17. A Straightforward Synthesis of Polyfluorinated Furan Derivatives and Their Property
    Agou, T.; Nemoto, S.; Yamada, S.; Konno, T.; Mizuhata, Y.; Tokitoh, N.; Ebina, R.; Ishii, A.; Hosoya, T.; Fukumoto, H.; Kubota, T. Asian J. Org. Chem. 2018, 7, 2484-2489. DOI: 10.1002/ajoc.201800454.
  18. Facile transformation of 2H,3H-decafluoropentane (HFC-4310mee) into (Z)-2H-nonafluoropent-2-ene and its application to the synthesis of polyfluorinated homoallylic ketons by Claisen rearrangement
    Agou, T.; Aso, D.; Kataoka, S.; Tuchimochi, R.; Fukumoto, H.; Yamazaki, T.; Kawasaki-Takasuka, T.; Mizuhata, Y.; Tokitoh, N.; Kubota, T. J. Fluorine Chem. 2018, 213, 74-79. DOI: 10.1016/j.jfluchem.2018.07.006.
  19. Syntheses and Structures of d10 Coinage Metal Complexes of Electron-Accepting Phosphine Ligands Featuring a 3,3,4,4,5,5-Hexafluorocyclopentene Framework
    Agou, T.; Wada, N.; Fujisawa, K.; Hosoya, T.; Mizuhata, Y.; Tokitoh, N.; Fukumoto, H.; Kubota, T. Inorg. Chem. 2018, 57, 9105-9114. DOI: 10.1021/acs.inorgchem.8b01111.
  20. Synthesis of a new highly-fluorinated cis-1,2-cyclopentandiol and its application for fluorinated oligoesters
    Agou, T.; Ohata, R.; Mizuhata, Y.; Tokitoh, N.; Fukumoto, H.; Kubota, T. J. Fluorine Chem. 2018, 210, 78-82. DOI: 10.1016/j.jfluchem.2018.03.002.
福元(茨城大着任以降)
    2017年
  1. Efficient Synthesis of Fluorinated Phenanthrene Monomers Using Mallory Reaction and Their Copolymerization
    Fukumoto, H.; Ando, M.; Shiota, T.; Izumiya, H.; Kubota, T. Macromolecules 2017, 50, 865-871.
  2. 2014年
  3. Preparation and chemical properties of poly(1,10-phenanthroline-3,8-diyl)s with crown ethereal subunits
    Fukumoto, H.; Kase, Y.; Koizumi, T.; Yamamoto, T. React. Funct. Polym. 2014, 82, 9-16.
  4. Preparation and chemical properties of π-conjugated polymers containing indigo unit in the polymer main chain
    Fukumoto, H.; Nakajima, K.; Kojima, T.; Yamamoto, T. Materials 2014, 7, 2030-2043.
  5. 2013年
  6. Preparation of π-conjugated polymers consisting of 1-aminopyrrole and 4-amino-1,2,4-triazole units Koie, S.; Tanaka, G.; Fukumoto, H.; Koizumi, T.; Yamamoto, T. Reac. Funct. Polym. 2013, 73, 1180-1187.
  7. Effects of solvent and temperature on regioregularity of poly(3-hexylthiophene-2,5-diyl) prepared by chemical oxidative polymerization
    Fukumoto, H.; Omori, Y.; Yamamoto, T. Polym. J. 2013, 45, 462-465.
  8. 2012年
  9. Copolymers of pyrrole with N-alkynylpyrroles
    Yamamoto, T.; Yamagata, Y.; Yamashita, R.; Abla, M.; Fukumoto, H.; Koizumi, T. Synth. Met. 2012, 162, 2406-2413.
  10. Preparation of dibromopyridines having -(CH2)m-SO3Na group(s) as monomers for new polypyridines
    Takei, T.; Ohki, T. Harada, Y.; KUmagai, N.; Fukumoto, H. ;Koizumi, T.; Maeda, A.; Kojima, T.; Sei, Y.; Shiramizu, K.; Abe, M.; Oota, M.; Yamamoto, T. Tetrahedron Lett. 2012, 53, 5907-5910.
  11. Field-effect transistors of the block co-oligomers based on thiophene and pyridine
    Haemori, M.; Itaka, K.; Yamaguchi, J.; Kumagai, A.; Yaginuma, S.; Fukumoto, H.; Matsumoto, Y.; Yamamoto, T.; Koinuma, H. Thin Solid Films 2012, 520, 4445-4448.
  12. 2011年
  13. π-Conjugated Polymers Consisting of 9,10-Dihydrophenanthrene Units
    Yamamoto, T.; Tokimitsu, R.; Asao, T.; Iijima, T.; Fukumoto, H.; Koizumi, T.; Fukuda, T.; Ushijima, H. Macromol. Chem. Phys. 2011, 212, 2406-2416.
  14. Preparation of Head-to-tail π-Conjugated Poly(thiophene-pyridine) and Poly(pyrimidine) by Organometallic Polycondensation
    Fukumoto, H.; Fujiwara, Y.; Yamamoto, T. Chem. Lett. 2011, 40, 992-994.
  15. Bithiophene-Bithiazole Alternating Copolymers with Thiophene Side Chains: Synthesis by Orgaonmetallic Polycondensation and Chemical Properties of the Copolymers
    Yamamoto, T; Otsuka, S.-i.; Fukumoto, H.; Sakai, Y.; Aramaki, S.; Fukuda, T.; Emoto, A.; Ushijima, H. J. Polym. Sci. Part A: Polym. Chem. 2011, 49, 1508-1512.
  16. 2010年
  17. π-Conjugated Poly(aryleneethynylene)s Consisting of Salophen and Ni-Salophen Units in the π-Conjugated Main Chain: Preparation and Chemical Properties
    Fukumoto, H.; Yamane, K.; Kase, Y.; Yamamoto, T. Macromolecules 2010, 43, 10366-10375.
  18. Molecular Beam Deposition of Nanoscale Ionic Liquids in Ultrahigh Vacuum
    Maruyama, S.; Takeyama, Y.; Taniguchi, H.; Fukumoto, H.; Itoh, M.; Kumigashira, H.; Oshima, M.; Yamamoto, T.; Matsumoto, Y. ACS nano 2010, 4, 5946-5952.
  19. Synthesis of New Thiophene-Based π-Conjugated Organic Compounds and Polymer
    Usui, M.; Fukumoto, H.; Yamamoto, T. Bull. Chem. Soc. Jpn. 2010, 83, 1397-1399.
  20. π-Conjugated Polymers Consisting of Isothianaphthene and Dialkoxy-p-phenylene Units: Synthesis, Self-Assembly, and Chemical and Physical Properties
    Yamamoto, T.; Usui, M.; Ootsuka, H.; Iijima, T.; Fukumoto, H.; Sakai, Y.; Aramaki, S.; Yamamoto, H. M.; Yagi, T.; Tajima, H.; Okada, T.; Fukuda, T.; Emoto, A.; Ushijima, H.; Hasegawa, M.; Ohtsu H. Macromol. Chem. Phys. 2010, 211, 2138-2147.
  21. Ionic polymers and oligomers with expanded π-conjugation system derived from through-space interaction in piperazinium ring
    Yamaguchi, I; Kado, A; Fukuda, T.; Fukumoto, H.; Yamamoto, T.; Sato, M. 0Eur. Polym. J. 2010, 46, 1119-1130.
吾郷(茨城大着任以降)
    2021年
  1. Construction of CF3-Containing Quaternary Chiral Centers via Michael Addition Reactions
    Yamazaki, T.; Taketsugi, M.; Kawasaki-Takasuka, T.; Agou, T.; Kubota, T. Bull. Chem. Soc. J. 2021, 94, 1815-1822. DOI: 10.1246.bcsj.20210136.
  2. Synthesis, structural characterization, and reactivity of a dinuclear cobalt(II) (μ-hydroxo) (μ-pyrazolato) complex based on a hydrotris(pyrazolyl)borate ligand
    Komatsuzaki, H.; Ohira, K.; Tadokoro, S.; Yamasaki, Y.; Oouchi, H.; Satoh, M.; Agou, T.; Tanaka, Y.; Akita, M.; Nakazawa, J.; Hikichi, S.Inorg. Chim. ActaDOI: 10.1016/j.ica.2021.120533.
  3. Perfluorophenyl-Perfluorophenyl Stacking-Promoted Aggregation-Induced Emission Enhancement of Crystalline 5-Aryloxy-3H-Indole
    Funabiki, K.; Yamada, K.; Matsueda, H.; Arisawa, Y.; Agou, T.; Kubota, Y.; Inuzukka, T.; Wasada, H. Eur. J. Org. Chem. 2021, 1344-1350. DOI:10.1002/adsc.202001433.
  4. Practical Synthesis of α‐Trifluoromethylated Pyridines Based on Regioselective Cobalt‐Catalyzed [2+2+2] Cycloaddition using Trifluoromethylated Diynes with Nitriles
    Kumon, T.; Yamada, S.; Agou, T.; Fukumoto, H.; Kubota, T.; Hammond, G. B.; Konno, T. Adv. Synth. Cat. in press. DOI:10.1002/ejoc.202001638
  5. 2020年
  6. Syntheses of α-CF3-α-quaternary ketones via p-quinone methides and their derivatization to compounds with successively congested stereogenic centers
    Terashima, K.; Kawasaki-Takasuka, T.; Agou, T.; Kubota, T.; Yamazaki, T. Org. Biomol. Chem. 2020, 18, 4638-4644. DOI: 10.1039/D0OB00951B.
  7. 1,2‐Disubstituted 3,3,4,4,5,5‐hexafluorocyclopentenes as bent light-emitting π-conjugated luminophores
    Yamada, S.; Nishizawa, A.; Agou, T.; Kubota, T.; Konno, T. Eur. J. Org. Chem. 2020, 870-877. DOI: 10.1002/ejoc.201901794.
  8. 2019年
  9. Reaction of Dialumane Incorporating Bulky Eind Groups with Pyridines
    Murosaki, T.; Ohno, R.; Agou, T.; Hashizume, D.; Matsuo, T. Inorganics 2019, 7, 129. DOI: 10.3390/inorganics7110129.
  10. 2018年
  11. Divergent pathways for reactions of CF3-containing isobenzofuran-1-ones and amines
    Mitobe, K.; Kasawaki-Takasuka, T.; Agou, T.; Kubota, T.; Yamazaki, T. J. Fluorine Chem. 2018, 218, 36-41. DOI: 10.1016/j.jfluchem.2018.11.012.
  12. Preparation and reactions of CF3-containing phthalides
    Mitobe, K.; Terashima, K.; Kawasaki-Takasuka, T.; Agou, T.; Kubota, T.; Yamazaki, T. Eur. J. Org. Chem. 2018, 6944-6951. DOI: 10.1002/ejoc.201801384.
  13. A Monomeric Manganese(II) Catecholato Complex: Synthesis, Crystal Structure, and Reactivity toward Molecular Oxygen
    Agake, S.; Komatsuzaki, H.; Satoh, M.; Agou, T.; Tanaka, Y.; Akita, M.; Nakazawa, J.; Hikichi, S. Inorg. Chim. Acta 2018, 484, 424-429. DOI: 10.1016/j.ica.2018.09.013
  14. Stereoselective Aldol Reactions Using Pseudo C2 Symmetric 1-Benzyl-4-(trifluoromethyl)piperidine-2,6-dione
    Inoue, Y.; Hatayama, T.; Kawasaki-Takasuka, T.; Agou, T.; Kubota, T.; Yamazaki, T. Chem. Commun. 2018, 54, 9913-9916. DOI: 10.1039/c8cc05458d.
  15. Development of Novel Solid-State Light-Emitting Materials Based on Pentafluorinated Tolane Fluorophores
    Yamada, S.; Mitsuda, A.; Miyano, K.; Tanaka, T.; Morita, M.; Agou, T.; Kubota, T.; Konno, T. ACS Omega 2018, 3, 9105-9113. DOI: 10.1021/acsomega.8b01490.
  16. Thermoresponsive luminescence properties of polyfluorinated bistolane-type light-emitting liquid crystals
    Yamada, S.; Morita, M.; Agou, T.; Kubota, T.; Ichikawa, T.; Konno, T. Org. Biomol. Chem. 2018, 16, 5609-5617. DOI: 10.1039/c8ob01497c.
  17. Highly regioselective cobalt-catalyzed [2+2+2] cycloaddition of fluorine-containing internal alkynes to construct various fluoroalkylated benzene derivatives
    Kumon, T.; Yamada, S.; Agou, T.; Kubota, T.; Konno, T. J. Fluorine Chem. 2018, 213, 11-17. DOI: 10.1016/j.jfluchem.2018.06.004.
  18. Synthesis and Structure of Lewis Base-coordinated Phosphanylalumanes Bearing P-H and Al-Br Moieties
    Agou, T.; Ikeda, S.; Sasamori, T.; Tokitoh, N. Eur. J. Inorg. Chem. 2018, 1984-1987. DOI: 10.1002/ejic.201800175.
  19. Synthesis and Characterization of N-Heterocyclic Carbene-Coordinated Silicon Compounds Bearing a Fused-Ring Bulky Eind Group
    Hayakawa, N.; Sadamori, K.; Mizutani, S.; Agou, T.; Sugahara, T.; Sasamori, T.; Tokitoh, N. Hashizume, D.; Matsuo, T. Inorganics 2018, 6, 30. DOI: 10.3390/inorganics6010030.
  20. 2017年
  21. Fluorine-containing bistolanes as light-emitting liquid crystalline molecules
    Yamada, S.; Miyano, K.; Konno, T.; Agou, T.; Kubota, T.; Hosokai, T. Org. Biomol. Chem. 2017, 15, 5949-5948. DOI: 10.1021/acs.joc.6b02793.
  22. Stereochemically Defined Multisubstituted Alkenes Bearing a Tetrafluoroethylene (-CF2-CF2-) Fragment
    Sakaguchi, Y.; Yamada, S.; Konno, T.; Agou, T.; Kubota, T. J. Org. Chem. 2017, 82, 1618-1631. DOI: 10.1021/acs.joc.6b02793.
  23. 2016年
  24. Synthesis of a 1-Aryl-2,2-chlorosilyl(phospha)silene Coordinated by an N-Heterocyclic Carbene
    Kyri, A. W.; Kumar Majhi, P.; Sasamori, T.; Agou, T.; Nesterov, V.; Nagase, S.; Guo, J.-D.; Tokitoh, N.; Streubel, R. Molecules 2016, 21, 1309. DOI: 10.3390/molecules21101309.
  25. Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species
    Nagata, K.; Murosaki, T.; Agou, T.; Sasamori, T.; Matsuo, T.; Tokitoh, N. Angew. Chem. Int. Ed. 2016, 55, 12877-12880.DOI: 10.1002/anie.201607772.
  26. Synthesis and Structure of an Iron-Bromoalumanyl Complex with a Tri-Coordinated Aluminum Center
    Agou, T.; Yanagisawa, T.; Sasamori, T.; Tokitoh, N. Bull. Chem. Soc. J. 2016, 89, 1184-1186. DOI: 10.1246/bcsj.20160151.

特許

グループ共同
  1. 含フッ素スチレン誘導体及びその重合体並びにその製造方法、特願2021-036994(2021年3月9日出願)
  2. 含フッ素重合体及びその製造方法、特願2021-034126(2021年3月4日出願)
  3. フッ素置換基を有する多環芳香族複素環式化合物の製法、特願2019-206329(2019年11月14日出願)、特開2021-80179(2021年5月27日公開)
  4. フッ素置換基を有する多環芳香族炭化水素化合物の製法、特願2019-206327(2019年11月14日出願)、特開2021-80178(2021年5月27日公開)
  5. フッ素置換基を有するヘリセン類の製法、特願2019-046369(2019年3月13日出願)
  6. 含フッ素芳香族化合物及びその製造方法、特願2019-028738(2019年2月20日出願)
  7. 含フッ素重合体、特願2019-19004(2019年2月5日出願)
  8. ビスホスフィノヘキサフルオロシクロペンテン誘導体、その製造方法、遷移金属錯体及びそれを用いた有機化合物の製造方法、特願2018-246660(2018年12月2日出願)
  9. 含フッ素多環芳香族化合物、有機薄膜トランジスタ、太陽電池、電子写真感光体及び有機発光素子の製造方法、特願2018-174910(2018年9月19日出願)、特開2020-070289(2020年5月7日公開)
  10. 含フッ素環状ジオールを原料としたエステル類およびアリルエーテル類の製造法、特願2018-200162(2018年10月24日出願)、特開2020-66596(2020年4月30日公開)
  11. 含フッ素環状ジオールを原料としたエステル類およびアリルエーテル類の製造法、特願2018-200160(2018年10月24日出願)、特開2020-66595(2020年4月30日公開)
  12. フッ素置換基を有する含硫黄多環芳香族化合物の製法、特願2018-182446(2018年9月27日出願)、特開2020-50618(2020年4月2日公開)
  13. 含フッ素アルキン化合物及びその製造方法、並びに製造用中間体、特願2019-044878(2018年3月12日出願)、特開2019-172659(2019年10月10日公開)
  14. 含フッ素シクロアルカンジオールおよび製造方法、特願2017-237198(2017年12月11日出願)、特開2019-104697(2019年6月27日公開)
  15. 含フッ素π共役系環状高分子の製造方法と該製造方法によって得られる含フッ素π共役系環状高分子を用いた発光素子、特願2017-74148(2017年4月4日出願)、特開2018-177842(2018年11月15日公開)
  16. 新規な含フッ素環状有機化合物とその製造方法並びに前記含フッ素環状有機化合物からなる相間移動触媒、金属イオン捕捉剤、電解質形成材料、造影剤及び液浸露光プロセス用液体、特願2017-45573(2017年3月10日出願)、特開2018-150247(2018年9月27日公開)
福元
  1. 新規な含窒素複素環化合物、それよりなる電子輸送材料及びそれを含む有機発光素子と太陽電池、特開2016-060722(2016年4月25日公開)
  2. 縮合多環芳香族骨格を有するポリマー及びそれを用いた発光素子及び電極、特開2016-084448(2016年5月19日公開)
吾郷
  1. 変性ポリマーの製造方法、特願2015-155152(2015年8月5日出願)、特開2017-031370(2017年2月9日公開)

学会発表など